Dioctyl Sebacate
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Dioctyl-sebacate
Dioctyl-sebacate
General Info
Product Name
Dioctyl Sebacate
CAS NO.
122-62-3
Physical Properties
Product Name Dioctyl sebacate
Cas Number 122-62-3
Formula C26H50O4
Molar Mass 426.68 g/mol
Boiling Point 386 °C
Density 0.912 g/cm³
Flash Point 195 °C
Viscosity 14.6 mPa·s
Refractive Index 1.449
Vapor Pressure 0.037 mmHg
Solubility Water Insoluble
Appearance Colorless liquid
Odor Odorless
Pour Point -74 °C
FAQ
What is Dioctyl Sebacate, and what are its primary applications in industrial settings?

Dioctyl Sebacate, often abbreviated as DOS, is a diester of sebacic acid and 2-ethylhexanol. Known for its exceptional properties as a plasticizer, Dioctyl Sebacate helps in the formulation of flexible plastics, making it a crucial component in various industrial applications. This compound is favored for its excellent flexibility at low temperatures and its ability to impart significant softness and elasticity to end products. One of the primary applications of Dioctyl Sebacate is in the production of PVC (polyvinyl chloride) compounds, where it is particularly valued for maintaining flexibility even in cold environments.

In addition to its use in PVC, Dioctyl Sebacate finds a prominent place in industries producing synthetic rubbers. The compound helps enhance the low-temperature performance of rubber materials, making them suitable for applications where flexibility under cold conditions is a critical requirement. Sports and recreational equipment, automotive interiors, and insulation materials are some areas where synthetic rubbers with Dioctyl Sebacate are commonly used.

Furthermore, Dioctyl Sebacate is extensively adopted in the field of food packaging due to its non-toxic nature and compliance with food safety standards. It is used in the production of cling films and other flexible wraps that require assurance of non-reactivity with food substances. The ability of Dioctyl Sebacate to maintain flexibility over a broad temperature range helps in preserving the integrity of packaged goods even when they are subjected to the extremes of storage conditions.

The medical industry also exploits the unique properties of Dioctyl Sebacate. It is used in the manufacture of medical-grade tubing and blood bags, where flexibility and non-reactivity are crucial for maintaining the safety and functionality of these products. Its role in these sectors is underscored by its biocompatibility and capacity to meet stringent regulatory norms.

Beyond these applications, Dioctyl Sebacate's stability and resistance to weathering make it suitable for use in cable insulation, automotive parts, and coatings. Its contribution to enhancing the durability and performance of these products highlights its indispensable role in industrial settings. Taken together, the versatility and performance advantages of Dioctyl Sebacate ensure its continued popularity across a wide array of specialized and general industrial applications.

How is Dioctyl Sebacate produced, and what are its chemical properties?

Dioctyl Sebacate is synthesized through the esterification of sebacic acid with 2-ethylhexanol. This reaction involves the use of an acid catalyst, such as sulfuric acid, to facilitate the esterification process, which results in the formation of the ester bond. In a typical production process, sebacic acid is combined with two moles of 2-ethylhexanol in the presence of the catalyst. The mixture is then heated to initiate the reaction, leading to the formation of Dioctyl Sebacate along with water, which is removed to drive the reaction towards completion.

The chemical formula for Dioctyl Sebacate is C26H50O4, and it is a clear, colorless liquid at room temperature. Known for its excellent stability under a wide range of temperatures, it is highly resistant to oxidation and hydrolysis. Its molecular weight is approximately 426.68 g/mol, and it has a boiling point of around 531°F (277°C). The density of Dioctyl Sebacate is about 0.91 g/cm³, and its flashpoint varies between 380°F to 401°F (193°C to 205°C).

One of the essential chemical characteristics of Dioctyl Sebacate is its low volatility, which contributes to its utility in applications subject to significant temperature fluctuations. This low volatility ensures that Dioctyl Sebacate remains stable and does not lose its effectiveness as a plasticizer or lubricant under high-temperature conditions. Additionally, its low moisture uptake makes it suitable for applications exposed to humid or wet environments since it does not degrade or lose its plasticizing efficiency upon exposure to moisture.

In terms of optical properties, Dioctyl Sebacate has a refractive index of around 1.44. This characteristic is relevant when used in clear, flexible plastics where visual aesthetics and optical clarity are important. Moreover, its non-toxic and relatively inert nature makes it compatible for use in direct contact with food and medical materials, as it does not leach harmful substances or react with packaged or stored products.

The production and chemical features of Dioctyl Sebacate render it highly effective in not only traditional applications but also in emerging fields that demand environmentally benign plasticizers. Its properties align well with the growing emphasis on sustainable and safe chemical processes and products, further enhancing its attractiveness as a versatile industrial compound.

What are the environmental considerations associated with Dioctyl Sebacate?

Dioctyl Sebacate, being an organic compound primarily employed as a plasticizer, must be evaluated for its environmental impact throughout its lifecycle—from production to disposal. The environmental considerations associated with Dioctyl Sebacate start with the sourcing of its raw materials. Sebacic acid, a key precursor, is traditionally derived from castor oil, which links its production to agricultural practices. Hence, the environmental impact of cultivating castor plants, including soil quality, water usage, and pesticide application, must be taken into account. Sustainable agricultural practices and choosing non-toxic catalysts for its production process can mitigate initial environmental effects.

During its synthesis, the production of Dioctyl Sebacate should ideally be part of a green chemistry approach to minimize waste and energy consumption. Employing renewable energy sources and implementing recycling programs for production byproducts can significantly lower the carbon footprint of its manufacturing process. In addition, eliminating or reducing the use of harmful organic solvents improves the safety and environmental profile of the production process, aligning with global environmental regulations and sustainability goals.

In terms of its contribution to pollution, Dioctyl Sebacate is considered relatively benign, as it is less volatile and thus less likely to contribute to air pollution than some other plasticizers. Additionally, due to its chemical stability and low water solubility, it has minimal direct detrimental effects on aquatic environments if accidentally released. Its biodegradability is another important consideration—while Dioctyl Sebacate exhibits a moderate rate of biodegradation, optimizing formulations to enhance its environmental breakdown can lead to reduced persistence in natural settings.

Its utility in products that demand flexibility without compromising environmental safety, such as food packaging and consumer goods, highlights its relevance in eco-conscious applications. However, the ultimate environmental impact depends on the end product lifecycle management. Recycling and proper disposal of products containing Dioctyl Sebacate are vital, as improper disposal can lead to plastic accumulation in landfills. Efforts to develop recycling systems that incorporate recovery and reuse of Dioctyl Sebacate from discarded products can further alleviate environmental concerns.

Overall, while Dioctyl Sebacate shows promise for environmentally friendly application due to its non-toxic nature and lower volatile emissions, it is crucial for manufacturers and users to engage in responsible production, use, and disposal practices. A comprehensive approach that addresses every stage of its lifecycle ensures that Dioctyl Sebacate remains a sustainable choice in a world progressively inclined toward reducing environmental impacts.

What are the advantages of using Dioctyl Sebacate as a plasticizer in comparison to other alternatives?

Dioctyl Sebacate offers several advantages as a plasticizer when compared to other alternatives, making it a favored choice across various industries that require flexible yet durable materials. The primary advantage of Dioctyl Sebacate is its superior performance at low temperatures. Many plasticizers lose their efficiency and flexibility when exposed to lower temperatures, whereas Dioctyl Sebacate maintains the flexibility and workability of the materials it is incorporated into, which is essential for applications that operate under cold conditions such as outdoor cables, automotive parts, and specialized cold-weather equipment.

Another significant advantage is its high resistance to volatility. Dioctyl Sebacate has a lower tendency to evaporate, ensuring that the physical and mechanical properties of the plastic remain stable over time. This characteristic is particularly crucial for products subjected to high-temperature conditions or strong sunlight exposure, such as automotive interiors and window sealants. With reduced evaporation, products maintain their desired flexibility and longevity, contributing to their reliability and performance integrity.

Dioctyl Sebacate is also known for its environmental friendliness relative to other commonly used plasticizers, such as phthalates, which have faced scrutiny due to health and environmental concerns. Dioctyl Sebacate does not leach harmful chemicals and is less likely to pose ecological hazards upon disposal or degradation. This feature aligns with the increasingly stringent regulatory landscape that governs plasticizer usage, making it suitable for applications that require compliance with health and environmental safety standards, including food contact materials and medical devices.

Moreover, the chemical stability of Dioctyl Sebacate provides a clear advantage, especially in applications like electrical cables and insulation materials, where resistance to chemical breakdown over time is crucial. Its compatibility with various polymers further broadens its application scope, ensuring consistent performance when mixed with other materials to form complex formulations needed for advanced industrial and consumer applications.

Additionally, the optical clarity imparted by Dioctyl Sebacate when used in transparent flexible materials enhances the aesthetic and functional qualities of products like packaging films and optical-grade sheets. The material remains clear and does not yellow over time, which is a common issue with some other plasticizer alternatives.

Overall, the combination of physical performance, environmental compliance, chemical stability, and wide applicability solidly positions Dioctyl Sebacate as an advantageous plasticizer. Industries looking to balance stringent regulatory compliance requirements with the need for high-performance, flexible materials increasingly turn to Dioctyl Sebacate, reflecting its proven utility and reliability across numerous specialized applications.