General Info
Product Name
Dioctyl Sebacate
Physical Properties
Product Name |
Dioctyl sebacate |
Cas Number |
122-62-3 |
Formula |
C26H50O4 |
Molar Mass |
426.68 g/mol |
Boiling Point |
386 °C |
Density |
0.912 g/cm³ |
Flash Point |
195 °C |
Viscosity |
14.6 mPa·s |
Refractive Index |
1.449 |
Vapor Pressure |
0.037 mmHg |
Solubility Water |
Insoluble |
Appearance |
Colorless liquid |
Odor |
Odorless |
Pour Point |
-74 °C |
FAQ
What is Dioctyl Sebacate, and what are its primary applications in industrial settings?
Dioctyl
Sebacate, often abbreviated as DOS, is a diester of sebacic acid and 2-ethylhexanol. Known for its
exceptional properties as a plasticizer, Dioctyl Sebacate helps in the formulation of flexible plastics,
making it a crucial component in various industrial applications. This compound is favored for its
excellent flexibility at low temperatures and its ability to impart significant softness and elasticity
to end products. One of the primary applications of Dioctyl Sebacate is in the production of PVC
(polyvinyl chloride) compounds, where it is particularly valued for maintaining flexibility even in cold
environments.
In addition to its use in PVC, Dioctyl Sebacate finds a prominent place in
industries producing synthetic rubbers. The compound helps enhance the low-temperature performance of
rubber materials, making them suitable for applications where flexibility under cold conditions is a
critical requirement. Sports and recreational equipment, automotive interiors, and insulation materials
are some areas where synthetic rubbers with Dioctyl Sebacate are commonly used.
Furthermore,
Dioctyl Sebacate is extensively adopted in the field of food packaging due to its non-toxic nature and
compliance with food safety standards. It is used in the production of cling films and other flexible
wraps that require assurance of non-reactivity with food substances. The ability of Dioctyl Sebacate to
maintain flexibility over a broad temperature range helps in preserving the integrity of packaged goods
even when they are subjected to the extremes of storage conditions.
The medical industry also
exploits the unique properties of Dioctyl Sebacate. It is used in the manufacture of medical-grade
tubing and blood bags, where flexibility and non-reactivity are crucial for maintaining the safety and
functionality of these products. Its role in these sectors is underscored by its biocompatibility and
capacity to meet stringent regulatory norms.
Beyond these applications, Dioctyl Sebacate's
stability and resistance to weathering make it suitable for use in cable insulation, automotive parts,
and coatings. Its contribution to enhancing the durability and performance of these products highlights
its indispensable role in industrial settings. Taken together, the versatility and performance
advantages of Dioctyl Sebacate ensure its continued popularity across a wide array of specialized and
general industrial applications.
How is Dioctyl Sebacate produced, and what are its chemical
properties?
Dioctyl Sebacate is synthesized through the esterification of sebacic acid with
2-ethylhexanol. This reaction involves the use of an acid catalyst, such as sulfuric acid, to facilitate
the esterification process, which results in the formation of the ester bond. In a typical production
process, sebacic acid is combined with two moles of 2-ethylhexanol in the presence of the catalyst. The
mixture is then heated to initiate the reaction, leading to the formation of Dioctyl Sebacate along with
water, which is removed to drive the reaction towards completion.
The chemical formula for
Dioctyl Sebacate is C26H50O4, and it is a clear, colorless liquid at room temperature. Known for its
excellent stability under a wide range of temperatures, it is highly resistant to oxidation and
hydrolysis. Its molecular weight is approximately 426.68 g/mol, and it has a boiling point of around
531°F (277°C). The density of Dioctyl Sebacate is about 0.91 g/cm³, and its flashpoint varies between
380°F to 401°F (193°C to 205°C).
One of the essential chemical characteristics of Dioctyl
Sebacate is its low volatility, which contributes to its utility in applications subject to significant
temperature fluctuations. This low volatility ensures that Dioctyl Sebacate remains stable and does not
lose its effectiveness as a plasticizer or lubricant under high-temperature conditions. Additionally,
its low moisture uptake makes it suitable for applications exposed to humid or wet environments since it
does not degrade or lose its plasticizing efficiency upon exposure to moisture.
In terms of
optical properties, Dioctyl Sebacate has a refractive index of around 1.44. This characteristic is
relevant when used in clear, flexible plastics where visual aesthetics and optical clarity are
important. Moreover, its non-toxic and relatively inert nature makes it compatible for use in direct
contact with food and medical materials, as it does not leach harmful substances or react with packaged
or stored products.
The production and chemical features of Dioctyl Sebacate render it highly
effective in not only traditional applications but also in emerging fields that demand environmentally
benign plasticizers. Its properties align well with the growing emphasis on sustainable and safe
chemical processes and products, further enhancing its attractiveness as a versatile industrial
compound.
What are the environmental considerations associated with Dioctyl
Sebacate?
Dioctyl Sebacate, being an organic compound primarily employed as a plasticizer, must
be evaluated for its environmental impact throughout its lifecycle—from production to disposal. The
environmental considerations associated with Dioctyl Sebacate start with the sourcing of its raw
materials. Sebacic acid, a key precursor, is traditionally derived from castor oil, which links its
production to agricultural practices. Hence, the environmental impact of cultivating castor plants,
including soil quality, water usage, and pesticide application, must be taken into account. Sustainable
agricultural practices and choosing non-toxic catalysts for its production process can mitigate initial
environmental effects.
During its synthesis, the production of Dioctyl Sebacate should ideally be
part of a green chemistry approach to minimize waste and energy consumption. Employing renewable energy
sources and implementing recycling programs for production byproducts can significantly lower the carbon
footprint of its manufacturing process. In addition, eliminating or reducing the use of harmful organic
solvents improves the safety and environmental profile of the production process, aligning with global
environmental regulations and sustainability goals.
In terms of its contribution to pollution,
Dioctyl Sebacate is considered relatively benign, as it is less volatile and thus less likely to
contribute to air pollution than some other plasticizers. Additionally, due to its chemical stability
and low water solubility, it has minimal direct detrimental effects on aquatic environments if
accidentally released. Its biodegradability is another important consideration—while Dioctyl Sebacate
exhibits a moderate rate of biodegradation, optimizing formulations to enhance its environmental
breakdown can lead to reduced persistence in natural settings.
Its utility in products that
demand flexibility without compromising environmental safety, such as food packaging and consumer goods,
highlights its relevance in eco-conscious applications. However, the ultimate environmental impact
depends on the end product lifecycle management. Recycling and proper disposal of products containing
Dioctyl Sebacate are vital, as improper disposal can lead to plastic accumulation in landfills. Efforts
to develop recycling systems that incorporate recovery and reuse of Dioctyl Sebacate from discarded
products can further alleviate environmental concerns.
Overall, while Dioctyl Sebacate shows
promise for environmentally friendly application due to its non-toxic nature and lower volatile
emissions, it is crucial for manufacturers and users to engage in responsible production, use, and
disposal practices. A comprehensive approach that addresses every stage of its lifecycle ensures that
Dioctyl Sebacate remains a sustainable choice in a world progressively inclined toward reducing
environmental impacts.
What are the advantages of using Dioctyl Sebacate as a plasticizer in
comparison to other alternatives?
Dioctyl Sebacate offers several advantages as a plasticizer
when compared to other alternatives, making it a favored choice across various industries that require
flexible yet durable materials. The primary advantage of Dioctyl Sebacate is its superior performance at
low temperatures. Many plasticizers lose their efficiency and flexibility when exposed to lower
temperatures, whereas Dioctyl Sebacate maintains the flexibility and workability of the materials it is
incorporated into, which is essential for applications that operate under cold conditions such as
outdoor cables, automotive parts, and specialized cold-weather equipment.
Another significant
advantage is its high resistance to volatility. Dioctyl Sebacate has a lower tendency to evaporate,
ensuring that the physical and mechanical properties of the plastic remain stable over time. This
characteristic is particularly crucial for products subjected to high-temperature conditions or strong
sunlight exposure, such as automotive interiors and window sealants. With reduced evaporation, products
maintain their desired flexibility and longevity, contributing to their reliability and performance
integrity.
Dioctyl Sebacate is also known for its environmental friendliness relative to other
commonly used plasticizers, such as phthalates, which have faced scrutiny due to health and
environmental concerns. Dioctyl Sebacate does not leach harmful chemicals and is less likely to pose
ecological hazards upon disposal or degradation. This feature aligns with the increasingly stringent
regulatory landscape that governs plasticizer usage, making it suitable for applications that require
compliance with health and environmental safety standards, including food contact materials and medical
devices.
Moreover, the chemical stability of Dioctyl Sebacate provides a clear advantage,
especially in applications like electrical cables and insulation materials, where resistance to chemical
breakdown over time is crucial. Its compatibility with various polymers further broadens its application
scope, ensuring consistent performance when mixed with other materials to form complex formulations
needed for advanced industrial and consumer applications.
Additionally, the optical clarity
imparted by Dioctyl Sebacate when used in transparent flexible materials enhances the aesthetic and
functional qualities of products like packaging films and optical-grade sheets. The material remains
clear and does not yellow over time, which is a common issue with some other plasticizer
alternatives.
Overall, the combination of physical performance, environmental compliance,
chemical stability, and wide applicability solidly positions Dioctyl Sebacate as an advantageous
plasticizer. Industries looking to balance stringent regulatory compliance requirements with the need
for high-performance, flexible materials increasingly turn to Dioctyl Sebacate, reflecting its proven
utility and reliability across numerous specialized applications.